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Stability of a eutectic interface during directional solidification

机译:定向凝固过程中共晶界面的稳定性

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摘要

Directional solidification of eutectic alloys shows different types of eutectic morphologies. These include lamellar, rod, oscillating and tilting modes. The growth of these morphologies occurs with a macroscopically planar interface. However, under certain conditions, the planar eutectic front becomes unstable and gives rise to a cellular or a dendritic structure. This instability leads to the cellular/dendritic structure of either a primary phase or a two-phase structure. The objective of this work is to develop a fundamental understanding of the instability of eutectic structure into cellular/dendritic structures of a single phase and of two-phases;Experimental studies have been carried out to examine the transition from a planar to two-phase cellular and dendritic structures in a ceramic system of Alumina-Zirconia (Al[subscript]2O[subscript]3-ZrO[subscript]2) and in a transparent organic system of carbon tetrabromide and hexachloroethane (CBr[subscript]4- C[subscript]2Cl[subscript]6). Several aspects of eutectic interface stability have been examined;Studies in the colony structures show that the planar eutectic temperature decreases as the velocity is increased. However, as the planar interface becomes unstable, the temperature of the two-phase cellular structure increases with velocity, goes through a maximum, and finally decreases as the cellular structure transforms into a two-phase dendritic structure. Careful experiments on both transparent as well as ceramic systems have shown deviations of the eutectic spacings in these colony structures from the planar interface model. Based on these results, a new model is proposed to explain the steady-state features of the colony growth;Experimental studies in the instability of eutectics into a single phase formation have shown that the interactions in the microstructures give rise to oscillations between the two stable morphologies around the threshold conditions. The effect of velocity on the oscillation has been examined quantitatively, and it was found that the oscillations decrease as the velocity is increased. A finite band of velocity was observed in which oscillating structures were found to exist. Furthermore, the composition of the alloy showed a large effect on the oscillation of the actual interface velocity which was found to increase as the alloy composition deviated further from the eutectic composition.
机译:共晶合金的定向凝固显示出不同类型的共晶形态。这些包括层状,杆状,振荡和倾斜模式。这些形态的增长发生在宏观平面界面上。然而,在某些条件下,平面共晶前沿变得不稳定,并引起细胞或树突结构。这种不稳定性导致初级相或两相结构的细胞/树突结构。这项工作的目的是对共晶结构不稳定性转变为单相和两相的细胞/树突结构的基本认识;已经进行了实验研究,以研究从平面相到两相细胞的转变。氧化铝-氧化锆(Al [下标] 2O [下标] 3-ZrO [下标] 2)陶瓷体系和四溴化碳与六氯乙烷的透明有机体系(CBr [下标] 4-C [下标])中的树枝状和树枝状结构2Cl [下标] 6)。研究了共晶界面稳定性的几个方面;菌落结构研究表明,平面共晶温度随着速度的增加而降低。然而,随着平面界面变得不稳定,两相蜂窝结构的温度随速度增加,经历最大值,最后随着蜂窝结构转变为两相树枝状结构而降低。在透明和陶瓷系统上进行的仔细实验表明,这些菌落结构中的共晶间距与平面界面模型之间存在偏差。基于这些结果,提出了一个新的模型来解释菌落生长的稳态特征;共晶不稳定性成单相形成的实验研究表明,微观结构中的相互作用引起了两个稳定结构之间的振荡。阈值条件周围的形态。定量研究了速度对振荡的影响,发现随着速度的增加,振荡减少。观察到有限的速度带,其中发现存在振荡结构。此外,合金的组成对实际界面速度的振荡表现出很大的影响,发现随着合金组成进一步偏离共晶组成而增加。

著录项

  • 作者

    Han, Seung Hoon;

  • 作者单位
  • 年度 1995
  • 总页数
  • 原文格式 PDF
  • 正文语种 en
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